1-(Ferrocen-1-ylmethyl)-3-methylimidazol-3-ium hexafluoridophosphate
نویسندگان
چکیده
The crystal structure of the title compound, [Fe(C(5)H(5))(C(10)H(12)N(2))]PF(6), consists of a ferrocene-1-methyl-(3-methyl-imidazolium) cation and a hexa-fluorido-phosphate anion. The ferrocenyl rings are skewed by 6.7 (4)° from the ideal eclipsed conformation. The inter-planar angle between the plane of the substituted cyclo-penta-dienyl ring and that of the imidazole ring is 89.9 (4)°. The crystal packing is stabilized by C-H⋯F hydrogen bonds.
منابع مشابه
1-(Ferrocen-1-ylmethyl)-3-methylimidazol-3-ium iodide
The structure of the title compound, [Fe(C5H5)(C10H12N2)]I, consists of a 1-(ferrocen-1-ylmeth-yl)-3-methyl-imidazolium cation which is counter-balanced by an iodide anion. The cyclo-penta-dienyl (Cp) rings of the ferrocene unit have a slightly staggered conformation skewed from an ideal eclipsed conformation by an angle of 3.5 (6)°. The inter-planar angle between the Cp and the imidazole ring ...
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